DNA-Protected Silver Clusters for Nanophotonics
نویسندگان
چکیده
منابع مشابه
DNA-Protected Silver Clusters for Nanophotonics
DNA-protected silver clusters (AgN-DNA) possess unique fluorescence properties that depend on the specific DNA template that stabilizes the cluster. They exhibit peak emission wavelengths that range across the visible and near-IR spectrum. This wide color palette, combined with low toxicity, high fluorescence quantum yields of some clusters, low synthesis costs, small cluster sizes and compatib...
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The relationship between the state of charge and spectroscopy of DNA-protected silver emitters is not yet well understood. This remains one of the major issues to unveil in order to fully disentangle the spectroscopic features of these novel systems. It is a well known fact that a fluorescence response arises upon chemical reduction of silver cations attached to DNA, leading to neutral (or part...
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Small silver clusters (average diameter of 1.2 nm) protected by 4-(tert-butyl)benzyl mercaptan (BBSH) were converted to stable, monodisperse clusters (2.1 nm) by a ripening process with excess amount of BBSH. Multiple characterizations of the isolated magic clusters revealed an approximate chemical composition of Ag(∼280)(SBB)(∼120).
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Details of the research undertaken in our laboratory can be found at http://www.dstuns.iitm.ac.in/pradeep-research-group.php. A green route to synthesise glutathione protected atomically precise silver clusters by sunlight irradiation of silver thiolates confi ned in gel cavities, and the antibacterial properties of the as-synthesized clusters against gram-negative and gram-positive bacteria. A...
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Nanometer-sized gold clusters stabilized by monolayers of arenethiolates prepared using the Brust reaction are somewhat larger (by TEM) and less thermally stable (by TGA) than those prepared under similar conditions and stabilized by alkanethiolates. Like the latter, the mean core size decreases for synthetic conditions based on larger thiol/Au ratios. The differential pulse voltammetry of the ...
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ژورنال
عنوان ژورنال: Nanomaterials
سال: 2015
ISSN: 2079-4991
DOI: 10.3390/nano5010180